Search results for "polarization [Upsilon(9460)]"

Theoretical study of the electronic spectrum of magnesium-porphyrin

1999

Multiconfigurational self-consistent field (SCF) and second order perturbation methods have been used to study the electronic spectrum of magnesium-porphyrin (MgP). An extended ANO-type basis set including polarization functions on all heavy atoms has been used. Four allowed singlet states of E1u symmetry have been computed and in addition a number of forbidden transitions and a few triplet states. The results lead to a consistent interpretation of the electronic spectrum, where the Q band contains one transition, the B band two, and the N band one. The computed transition energies are consistently between 0.1 and 0.5 too low compared to the measured band maxima. The source of the discrepan…

Assessment of a single-acquisition imaging sequence for oxygen-sensitive (3)He-MRI.

2001

MRI of the lungs using hyperpolarized helium-3 (3He) allows the determination of intrapulmonary oxygen partial pressures (pO2). The need to separate competing processes of signal loss has hitherto required two different imaging series during two different breathing maneuvers. In this work, a new imaging strategy to measure pO2 by a single series of consecutive scans is presented. The feasibility of the method is demonstrated in three healthy human volunteers. Maps and histograms of intrapulmonary pO2 are calculated. Changes in the oxygen concentration of the inhaled gas mixture are well reproduced in the histograms. Monte Carlo (MC) simulations of the temporal evolution of 3He hyperpolariza…

Accessibility of Protein-Bound Chlorophylls Probed by Dynamic Electron Polarization

2018

The possibility to probe the accessibility of sites of proteins represents an important point to explore their interactions with specific substrates in solution. The dynamic electron polarization of nitroxide radicals induced by excited triplet states of organic molecules is a phenomenon that is known to occur in aqueous solutions. The interaction within the radical-triplet pair causes a net emissive dynamic electron polarization of the nitroxide radical, that can be detected by means of time-resolved electron paramagnetic resonance (TR-EPR) spectroscopy. We have exploited this effect to prove the accessibility of chlorophylls bound to a protein, namely, the water-soluble chlorophyll protei…

Electrohydrodynamic instabilities and orientation of dielectric ellipsoids in low-conducting fluids.

2000

We study the dynamics of an ellipsoidal particle in a weakly conducting dielectric liquid when submitted to a dc electric field. At low field intensities, the particle long axis is aligned in the field direction. When the field strength is increased, we show that, depending on the initial orientation of the particle, there exist two stable orientations: the one with the long axis parallel to the field direction remains possible while a spinning state with the long axis perpendicular to the field appears. This last striking orientation is due to the finite Maxwell-Wagner polarization relaxation time. For sufficiently high field intensities, each state loses its stability and the particle dyn…

Conduction band polarization in some CMR materials

2000

First principles electronic structure calculations reveal certain important common features in the conduction band polarization of many of the newly examined colossal magnetoresistance (CMR) materials. Most CMR compounds seem to possess a localized, magnetic band slightly below the Fermi energy. This localized band transfers polarization to a relatively broad conduction band. The nature of the two bands in different systems can be quite distinct. In the perovskite-derived manganese oxides, the magnetic band is derived from $Mn t_{2g}$ states while the conduction band is derived from Mn e states. In the chalcospinel $Fe_{^0.^5}$ $Cu_{^0.^5}$ $Cr_{2}$$ S_{4}$ , the $Crt_{2g}$ states which are…

The Politicization of European Union Trade Policy: Radical-Left Euroskeptic Opposition to the Transatlantic Trade and Investment Partnership

2021

This study aims to analyze the correlation between radical-left Euroskeptic (RLE) activity and European Union (EU) trade policy by focusing on the Transatlantic Trade and Investment Partnership (TTIP). At the beginning of TTIP negotiations, the agreement was not high on political agendas and was not a major concern within European society. Thus, its salience was low. This initial lack of interest stemmed from the fact that the TTIP, as an economic and technical issue, did not draw public attention. This study shows that RLEs profoundly affected public opinion on the TTIP by increasing its salience during the European parliamentary elections in 2014 in France and Germany. Second, RLEs involv…

Polarization and Spectacle in the Spanish Political Talk Show ‘La Sexta Noche’ During the 2019 European Elections

2021

This article analyses how in the main political talk show on television in Spain, La Sexta Noche, the main themes of the European agenda were silenced or conditioned by the themes of the national, regional and local agenda during the last European elec-tions. The media debate was oriented towards an analysis of the results of national elections and the campaign for regional and local elections that al-lowed for a greater spectacle, thanks to the shock effect of such polarized ideol-ogies and the trivialization of national politics. This research has studied all the shows of the programme broad-cast as of the national elections on 28th April 2019 up until the European elections held on 26th …

Correction of cavity-induced errors in polarization charges of continuum solvation models

1998

POLARIZATION-BASED CAR DETECTION

2018

International audience; Road scene understanding is a vital task for driving assistance systems. Robust vehicle detection is a precondition for diverse applications particularly for obstacle avoidance and secure navigation. Color images provide limited information about the physical properties of the object. This results in unstable vehicle detection caused mainly from road scene complexity (strong reflexions, noises and radiometric distortions). Instead, polarimetric images, characteristic of the light wave, can robustly describe important physical properties of the object (e.g., the surface geometric structure, material and roughness etc). This modality gives rich physical informations wh…

Bio-Inspired Polarization Vision Techniques for Robotics Applications

2015

Researchers have been inspired by nature to build the next generation of smart robots. Based on the mechanisms adopted by the animal kingdom, research teams have developed solutions to common problems that autonomous robots faced while performing basic tasks. Polarization-based behaviour is one of the most distinctive features of some species of the animal kingdom. Light polarization parameters significantly expand visual capabilities of autonomous robots. Polarization vision can be used for most tasks of color vision, like object recognition, contrast enhancement, camouflage breaking, and signal detection and discrimination. In this chapter, the authors briefly cover polarization-based vis…